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In quantum mechanics, the exchange operator ^, also known as permutation operator, [1] is a quantum mechanical operator that acts on states in Fock space. The exchange operator acts by switching the labels on any two identical particles described by the joint position quantum state | x 1 , x 2 {\displaystyle \left|x_{1},x_{2}\right\rangle } . [ 2 ]
Permutations without repetition on the left, with repetition to their right. If M is a finite multiset, then a multiset permutation is an ordered arrangement of elements of M in which each element appears a number of times equal exactly to its multiplicity in M. An anagram of a word having some repeated letters is an example of a multiset ...
When A and B interact, the Pauli principle requires the antisymmetry of the total wave function, also under intermolecular permutations. The total system can be antisymmetrized by the total antisymmetrizer which consists of the (N A + N B)! terms in the group S N A +N B. However, in this way one does not take advantage of the partial ...
In chemistry, molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties , such as whether or not it has a dipole moment , as well ...
Given any set X and a collection G of bijections of X into itself (known as permutations) that is closed under compositions and inverses, G is a group acting on X. If X consists of n elements and G consists of all permutations, G is the symmetric group S n; in general, any permutation group G is a subgroup of the symmetric group of X.
This is the limit of the probability that a randomly selected permutation of a large number of objects is a derangement. The probability converges to this limit extremely quickly as n increases, which is why !n is the nearest integer to n!/e. The above semi-log graph shows that the derangement graph lags the permutation graph by an almost ...
A permutation group is a subgroup of a symmetric group; that is, its elements are permutations of a given set. It is thus a subset of a symmetric group that is closed under composition of permutations, contains the identity permutation, and contains the inverse permutation of each of its elements. [2]
It satisfies anti-symmetry requirements, and consequently the Pauli principle, by changing sign upon exchange of two fermions. [1] Only a small subset of all possible many-body fermionic wave functions can be written as a single Slater determinant, but those form an important and useful subset because of their simplicity.