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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Chloromethane, also called methyl chloride, Refrigerant-40, R-40 or HCC 40, is an organic compound with the chemical formula CH 3 Cl. One of the haloalkanes , it is a colorless, sweet-smelling, flammable gas.
Methanol is primarily converted to formaldehyde, which is widely used in many areas, especially polymers. The conversion entails oxidation: 2 CH 3 OH + O 2 → 2 CH 2 O + 2 H 2 O. Acetic acid can be produced from methanol. The Cativa process converts methanol into acetic acid. [35] Methanol and isobutene are combined to give methyl tert-butyl ...
Sodium methoxide is prepared by treating methanol with sodium: 2 Na + 2 CH 3 OH → 2 CH 3 ONa + H 2. The reaction is so exothermic that ignition is possible. The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol.
The main application of potassium methoxide is use as basic transesterification catalyst in biodiesel synthesis (as a 25-32% methanolic solution). Triglycerides of vegetable and animal origin are reacted with methanol in the presence of alkali metal methanolates to form the corresponding fatty methyl esters. [9] [3]
Methyl chloroformate hydrolyzes in water to form methanol, hydrochloric acid, and carbon dioxide. [3] This decomposition happens violently in the presence of steam, causing foaming. The compound decomposes in heat, which can liberate hydrogen chloride, phosgene, chlorine, or other toxic gases.
Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures: log 10 (P) = −(0.05223) a / T + b , where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
Base-catalyzed carbonylation of methanol with carbon monoxide to methyl formate This process, practiced commercially by BASF among other companies gives 96% selectivity toward methyl formate. The catalyst for this process is sensitive to water, which can be present in the carbon monoxide feedstock, which is commonly derived from synthesis gas .