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Group 1 (alkali metals) and Group 2 (alkaline earth metals) are quite sensitive to flame photometry due to their low excitation energies. Analysis of samples by flame photometer. In principle, it is a controlled flame test with the intensity of the flame color quantified by photoelectric circuitry. The intensity of the color will depend on the ...
The nature of the excited and ground states depends only on the element. Ordinarily, there are no bonds to be broken, and molecular orbital theory is not applicable. The emission spectrum observed in flame test is also the basis of flame emission spectroscopy, atomic emission spectroscopy, and flame photometry. [4] [13]
A flame during the assessment of calcium ions in a flame photometer. The sample of a material (analyte) is brought into the flame as a gas, sprayed solution, or directly inserted into the flame by use of a small loop of wire, usually platinum. The heat from the flame evaporates the solvent and breaks intramolecular bonds to create free atoms.
A laboratory flame photometer that uses a propane operated flame atomizer Liquid or dissolved samples are typically used with flame atomizers. The sample solution is aspirated by a pneumatic analytical nebulizer , transformed into an aerosol , which is introduced into a spray chamber, where it is mixed with the flame gases and conditioned in a ...
Flame ionization detectors cannot detect inorganic substances and some highly oxygenated or functionalized species like infrared and laser technology can. In some systems, CO and CO 2 can be detected in the FID using a methanizer , which is a bed of Ni catalyst that reduces CO and CO 2 to methane, which can be in turn detected by the FID.
The Hefner lamp, or in German Hefnerkerze, is a flame lamp used in photometry that burns amyl acetate. The lamp was invented by Friedrich von Hefner-Alteneck in 1884 and he proposed its use as a standard flame for photometric purposes with a luminous intensity unit of the Hefnerkerze (HK). The lamp was specified as having a 40 mm flame height ...
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Most continuous flow analyzers depend on color reactions using a flow through photometer, however, also methods have been developed that use ISE, flame photometry, ICAP, fluorometry, and so forth. Flow injection analyzer