Search results
Results From The WOW.Com Content Network
For example, from Fe 2+ + 2 e − ⇌ Fe(s) (–0.44 V), the energy to form one neutral atom of Fe(s) from one Fe 2+ ion and two electrons is 2 × 0.44 eV = 0.88 eV, or 84 907 J/(mol e −). That value is also the standard formation energy (∆ G f °) for an Fe 2+ ion, since e − and Fe( s ) both have zero formation energy.
In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
Ionic potential is the ratio of the electrical charge (z) to the radius (r) of an ion. [1]= = As such, this ratio is a measure of the charge density at the surface of the ion; usually the denser the charge, the stronger the bond formed by the ion with ions of opposite charge.
The electric potential and the magnetic vector potential together form a four-vector, so that the two kinds of potential are mixed under Lorentz transformations. Practically, the electric potential is a continuous function in all space, because a spatial derivative of a discontinuous electric potential yields an electric field of impossibly ...
Since the electrons move about 600 times as fast as the ions, 600 times as many electrons will strike the wire as ions. If the wire is insulated it must assume such a negative potential that it receives equal numbers of electrons and ions, that is, such a potential that it repels all but 1 in 600 of the electrons headed for it."
The electrostatic potential energy, E pair, between a pair of ions of equal and opposite charge is: = where z = magnitude of charge on one ion e = elementary charge, 1.6022 × 10 −19 C ε 0 = permittivity of free space 4 π ε 0 = 1.112 × 10 −10 C 2 /(J·m)
The electric potential also varies with temperature, concentration and pressure. Since the oxidation potential of a half-reaction is the negative of the reduction potential in a redox reaction, it is sufficient to calculate either one of the potentials. Therefore, standard electrode potential is commonly written as standard reduction potential.
First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion. The latter can be regarded as the ionization energy of the –1 ion or the zeroth ionization energy. [1]