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Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...
Similar to the Kelvin scale, which was first proposed in 1848, [1] zero on the Rankine scale is absolute zero, but a temperature difference of one Rankine degree (°R or °Ra) is defined as equal to one Fahrenheit degree, rather than the Celsius degree used on the Kelvin scale.
On the empirical temperature scales that are not referenced to absolute zero, a negative temperature is one below the zero point of the scale used. For example, dry ice has a sublimation temperature of −78.5 °C which is equivalent to −109.3 °F. [97] On the absolute Kelvin scale this temperature is 194.6 K.
This convention means that temperature and energy quantities have the same dimensions. [51] [52] In particular, the SI unit kelvin becomes superfluous, being defined in terms of joules as 1 K = 1.380 649 × 10 −23 J. [53] With this convention, temperature is always given in units of energy, and the kelvin unit is not explicitly needed in ...
As a result, simple dimensional analysis can lead to errors if it is ambiguous whether 1 K means the absolute temperature equal to −272.15 °C, or the temperature difference equal to 1 °C. Orientation and frame of reference
is the absolute temperature of the gas, N {\displaystyle N} is the number of particles (usually atoms or molecules) of the gas. In SI units , p is measured in pascals , V is measured in cubic metres , n is measured in moles , and T in kelvins (the Kelvin scale is a shifted Celsius scale , where 0 K = −273.15 °C, the lowest possible ...
This definition also precisely related the Celsius scale to the Kelvin scale, which defines the SI base unit of thermodynamic temperature with symbol K. Absolute zero, the lowest temperature possible, is defined as being exactly 0 K and −273.15 °C. Until 19 May 2019, the temperature of the triple point of water was defined as exactly 273.16 ...
Here, U is internal energy, T is absolute temperature, S is entropy, P is pressure, and V is volume. This is only one expression of the fundamental thermodynamic relation. It may be expressed in other ways, using different variables (e.g. using thermodynamic potentials). For example, the fundamental relation may be expressed in terms of the ...