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Formally, the wavelength version of Wien's displacement law states that the spectral radiance of black-body radiation per unit wavelength, peaks at the wavelength given by: = where T is the absolute temperature and b is a constant of proportionality called Wien's displacement constant, equal to 2.897 771 955... × 10 −3 m⋅K, [1] [2] or b ...
Diagram illustrating the relationship between the wavenumber and the other properties of harmonic waves. In the physical sciences, the wavenumber (or wave number), also known as repetency, [1] is the spatial frequency of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber).
This equation is known as the Planck relation. Additionally, using equation f = c/λ, = where E is the photon's energy; λ is the photon's wavelength; c is the speed of light in vacuum; h is the Planck constant; The photon energy at 1 Hz is equal to 6.626 070 15 × 10 −34 J, which is equal to 4.135 667 697 × 10 −15 eV.
The wavelength and frequency peaks are in bold and occur at 25.0% and 64.6% respectively. The 41.8% point is the wavelength-frequency-neutral peak (i.e. the peak in power per unit change in logarithm of wavelength or frequency).
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
The name "dispersion relation" originally comes from optics. It is possible to make the effective speed of light dependent on wavelength by making light pass through a material which has a non-constant index of refraction, or by using light in a non-uniform medium such as a waveguide. In this case, the waveform will spread over time, such that ...
The refractive index, , can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is v = c/n, and similarly the wavelength in that medium is λ = λ 0 /n, where λ 0 is the wavelength of that light in vacuum.