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The combination principle is explained using quantum theory. Light consists of photons whose energy E is proportional to the frequency ν and wavenumber of the light: E = hν = hc/λ (where h is the Planck constant, c is the speed of light, and λ is the wavelength. A combination of frequencies or wavenumbers is then equivalent to a combination ...
For example, a wavenumber in inverse centimeters can be converted to a frequency expressed in the unit gigahertz by multiplying by 29.979 2458 cm/ns (the speed of light, in centimeters per nanosecond); [5] conversely, an electromagnetic wave at 29.9792458 GHz has a wavelength of 1 cm in free space.
Formally, the wavelength version of Wien's displacement law states that the spectral radiance of black-body radiation per unit wavelength, peaks at the wavelength given by: = where T is the absolute temperature and b is a constant of proportionality called Wien's displacement constant, equal to 2.897 771 955... × 10 −3 m⋅K, [1] [2] or b ...
In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
For periodic waves in nondispersive media (that is, media in which the wave speed is independent of frequency), frequency has an inverse relationship to the wavelength, λ . Even in dispersive media, the frequency f of a sinusoidal wave is equal to the phase velocity v of the wave divided by the wavelength λ of the wave: f = v λ ...
The name "dispersion relation" originally comes from optics. It is possible to make the effective speed of light dependent on wavelength by making light pass through a material which has a non-constant index of refraction, or by using light in a non-uniform medium such as a waveguide. In this case, the waveform will spread over time, such that ...
The refractive index, , can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is v = c/n, and similarly the wavelength in that medium is λ = λ 0 /n, where λ 0 is the wavelength of that light in vacuum.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.