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In statistical mechanics, the mean squared displacement (MSD, also mean square displacement, average squared displacement, or mean square fluctuation) is a measure of the deviation of the position of a particle with respect to a reference position over time.
The particle's Mean squared displacement from its original position is: =, where is the dimension of the particle's Brownian motion. For example, the diffusion of a molecule across a cell membrane 8 nm thick is 1-D diffusion because of the spherical symmetry; However, the diffusion of a molecule from the membrane to the center of a eukaryotic ...
The MSE either assesses the quality of a predictor (i.e., a function mapping arbitrary inputs to a sample of values of some random variable), or of an estimator (i.e., a mathematical function mapping a sample of data to an estimate of a parameter of the population from which the data is sampled).
There are two parts to Einstein's theory: the first part consists in the formulation of a diffusion equation for Brownian particles, in which the diffusion coefficient is related to the mean squared displacement of a Brownian particle, while the second part consists in relating the diffusion coefficient to measurable physical quantities. [12]
Physical scientists often use the term root mean square as a synonym for standard deviation when it can be assumed the input signal has zero mean, that is, referring to the square root of the mean squared deviation of a signal from a given baseline or fit. [8] [9] This is useful for electrical engineers in calculating the "AC only" RMS of a signal.
Algorithms for calculating variance; B. ... Mean squared displacement; ... Root mean square deviation of atomic positions; S. Skewness;
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For the mean square displacement along unit vector ^, simply take ^ ^. Related schemes use the parameters or B rather than (see to Trueblood et al. [6] for a more complete discussion). Finally, we can find the relationship between the Debye–Waller factor and the anisotropic displacement parameter.