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  2. Degenerate energy levels - Wikipedia

    en.wikipedia.org/wiki/Degenerate_energy_levels

    This leads to the general result of + and summing over all leads to the degeneracy of the -th state, = (+) = (+) (+) For the ground state =, the degeneracy is so the state is non-degenerate. For all higher states, the degeneracy is greater than 1 so the state is degenerate.

  3. Multiplicity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Multiplicity_(chemistry)

    In the ground state of dioxygen, this energy level is occupied by two electrons of the same spin, as shown in the molecular orbital diagram. The molecule, therefore, has two unpaired electrons and is in a triplet state. In contrast, the first and second excited states of dioxygen are both states of singlet oxygen. Each has two electrons of ...

  4. Stark effect - Wikipedia

    en.wikipedia.org/wiki/Stark_effect

    Not deterred by this prediction, Stark undertook measurements [3] on excited states of the hydrogen atom and succeeded in observing splittings. By the use of the Bohr–Sommerfeld ("old") quantum theory , Paul Epstein [ 4 ] and Karl Schwarzschild [ 5 ] were independently able to derive equations for the linear and quadratic Stark effect in ...

  5. Quantum harmonic oscillator - Wikipedia

    en.wikipedia.org/wiki/Quantum_harmonic_oscillator

    Second, these discrete energy levels are equally spaced, unlike in the Bohr model of the atom, or the particle in a box. Third, the lowest achievable energy (the energy of the n = 0 state, called the ground state) is not equal to the minimum of the potential well, but ħω/2 above it; this is called zero-point energy.

  6. Ground state - Wikipedia

    en.wikipedia.org/wiki/Ground_state

    The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum.

  7. Rotational spectroscopy - Wikipedia

    en.wikipedia.org/wiki/Rotational_spectroscopy

    The second factor is the degeneracy of the rotational state, which is equal to 2J + 1. This factor increases as J increases. Combining the two factors [18] (+) The maximum relative intensity occurs at [19] [notes 6]

  8. Spin isomers of hydrogen - Wikipedia

    en.wikipedia.org/wiki/Spin_isomers_of_hydrogen

    2 molecule, the spins of the two hydrogen nuclei (protons) couple to form a triplet state known as orthohydrogen, and a singlet state known as parahydrogen. The triplet orthohydrogen state has total nuclear spin I = 1 so that the component along a defined axis can have the three values M I = 1, 0, or −1.

  9. Excited state - Wikipedia

    en.wikipedia.org/wiki/Excited_state

    Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).