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Acetone (2-propanone or dimethyl ketone) is an organic compound with the formula (CH 3) 2 CO. [22] It is the simplest and smallest ketone (>C=O).It is a colorless, highly volatile, and flammable liquid with a characteristic pungent odour, very reminiscent of the smell of pear drops.
In organic chemistry, a ketone / ˈ k iː t oʊ n / is an organic compound with the structure R−C(=O)−R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group −C(=O)− (a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' is methyl), with the formula (CH 3) 2 CO ...
Acetone and acetic anhydride ((CH 3 C(O)) 2 O) upon the addition of boron trifluoride (BF 3) catalyst: [11] (CH 3 C(O)) 2 O + CH 3 C(O)CH 3 → CH 3 C(O)CH 2 C(O)CH 3 A second synthesis involves the base-catalyzed condensation (e.g., by sodium ethoxide CH 3 CH 2 O − Na + ) of acetone and ethyl acetate , followed by acidification of the sodium ...
Structure and properties Index of refraction, n D: 1.3561 Dielectric constant, ... Vapor pressure of acetone based on formula, = + from ...
Acetophenone is formed as a byproduct of the cumene process, the industrial route for the synthesis of phenol and acetone.In the Hock rearrangement of isopropylbenzene hydroperoxide, migration of a methyl group rather than the phenyl group gives acetophenone and methanol as a result of an alternate rearrangement of the intermediate:
It decomposes at a moderate reaction rate into acetone and carbon dioxide: CH 3 C(O)CH 2 CO 2 H → CH 3 C(O)CH 3 + CO 2. The acid form has a half-life of 140 minutes at 37 °C in water, whereas the basic form (the anion) has a half-life of 130 hours. That is, it reacts about 55 times more slowly. [8]
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Acetic anhydride, like most acid anhydrides, is a flexible molecule with a nonplanar structure. [4] The pi system linkage through the central oxygen offers very weak resonance stabilization compared to the dipole-dipole repulsion between the two carbonyl oxygens. The energy barriers to bond rotation between each of the optimal aplanar ...