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Ternary plots can also be used to create phase diagrams by outlining the composition regions on the plot where different phases exist. The values of a point on a ternary plot correspond (up to a constant) to its trilinear coordinates or barycentric coordinates.
The phase diagram shows, in pressure–temperature space, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. The curves on the phase diagram show the points where the free energy (and other derived properties) becomes non-analytic: their derivatives with respect to the coordinates (temperature and ...
A generic phase diagram with unspecified axes; the invariant point is marked in red, metastable extensions labeled in blue, relevant reactions noted on stable ends of univariant lines. This rule is geometrically sound in the construction of phase diagrams since for every metastable reaction, there must be a phase that is relatively stable. This ...
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
This violation is not a defect, rather it is the origin of the observed discontinuity in properties that distinguish liquid from vapor, and defines a first order phase transition. Figure 1: The curve is an isotherm, constant, in the --plane of a fluid that includes a phase change. The various segments of the curve are described in the text.
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
The N 2 chart or N 2 diagram (pronounced "en-two" or "en-squared") is a chart or diagram in the shape of a matrix, representing functional or physical interfaces between system elements. It is used to systematically identify, define, tabulate, design, and analyze functional and physical interfaces.
CALPHAD stands for Computer Coupling of Phase Diagrams and Thermochemistry, a methodology introduced in 1970 by Larry Kaufman, originally known as CALculation of PHAse Diagrams. [1] [2] [3] An equilibrium phase diagram is usually a diagram with axes for temperature and composition of a chemical system. It shows the regions where substances or ...