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The rule is relevant in understanding the emission spectrum of an excited molecule. Upon absorbing a photon, a molecule in its electronic ground state (denoted S 0, assuming a singlet state) may – depending on the photon wavelength – be excited to any of a set of higher electronic states (denoted S n where n>0).
The electron will reside in this energy level under normal circumstances, unless the ground state is full, in which case additional electrons will reside in higher energy states. If a photon of light hits the atom it will be absorbed if, and only if, energy of that photon is equal to the difference between the ground state and another energy ...
Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light ...
The energy content of this volume element at 5 km from the station is 2.1 × 10 −10 × 0.109 = 2.3 × 10 −11 J, which amounts to 3.4 × 10 14 photons per (). Since 3.4 × 10 14 > 1, quantum effects do not play a role. The waves emitted by this station are well-described by the classical limit and quantum mechanics is not needed.
In this case some of the energy can be captured to do work. If the electron is not kinetically isolated thermodynamics will take over and the products will react with each other to regenerate the ground state starting material. This process is called recombination and the photon's energy is released as heat. Recombination of photoinduced oxidation
The lifetime of a system in an excited state is usually short: spontaneous or induced emission of a quantum of energy (such as a photon or a phonon) usually occurs shortly after the system is promoted to the excited state, returning the system to a state with lower energy (a less excited state or the ground state). This return to a lower energy ...
The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum. If more ...
Then, the rule is that the amount of energy absorbed by an electron may allow for the electron to be promoted from a vibrational and electronic ground state to a vibrational and electronic excited state. A third rule is the Laporte Rule, which necessitates that the two energy states between which an electron transitions must have different ...