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Structural distortion analysis Determination of regular and irregular distorted octahedral molecular geometry; Octahedral distortion parameters [5] [6] [7] Volume of the octahedron; Tilting distortion parameter for perovskite complex [8] Molecular graphics. 3D modelling of complex; Display of the eight faces of octahedron
A perfect octahedron belongs to the point group O h. Examples of octahedral compounds are sulfur hexafluoride SF 6 and molybdenum hexacarbonyl Mo(CO) 6 . The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves.
This is an indexed list of the uniform and stellated polyhedra from the book Polyhedron Models, by Magnus Wenninger.. The book was written as a guide book to building polyhedra as physical models.
The Jahn–Teller effect (JT effect or JTE) is an important mechanism of spontaneous symmetry breaking in molecular and solid-state systems which has far-reaching consequences in different fields, and is responsible for a variety of phenomena in spectroscopy, stereochemistry, crystal chemistry, molecular and solid-state physics, and materials science.
The ideal tetrahedron, cube, octahedron, and dodecahedron form respectively the order-6 tetrahedral honeycomb, order-6 cubic honeycomb, order-4 octahedral honeycomb, and order-6 dodecahedral honeycomb; here the order refers to the number of cells meeting at each edge. However, the ideal icosahedron does not tile space in the same way.
A regular octahedron has 24 rotational (or orientation-preserving) symmetries, and 48 symmetries altogether. These include transformations that combine a reflection and a rotation. A cube has the same set of symmetries, since it is the polyhedron that is dual to an octahedron.
The octahedral plane is sometimes referred to as the 'pi plane' [10] or 'deviatoric plane'. [ 11 ] The octahedral profile is not necessarily constant for different values of pressure with the notable exceptions of the von Mises yield criterion and the Tresca yield criterion which are constant for all values of pressure.
Each octahedron is rotated by an equal (and opposite, within a pair) angle θ. It can be constructed by superimposing two compounds of four octahedra with rotational freedom , one with a rotation of θ , and the other with a rotation of − θ .