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  2. Logarithmic mean temperature difference - Wikipedia

    en.wikipedia.org/wiki/Logarithmic_mean...

    The LMTD is a steady-state concept, and cannot be used in dynamic analyses. In particular, if the LMTD were to be applied on a transient in which, for a brief time, the temperature difference had different signs on the two sides of the exchanger, the argument to the logarithm function would be negative, which is not allowable.

  3. UNIFAC - Wikipedia

    en.wikipedia.org/wiki/UNIFAC

    By adding a correction factor, known as the activity (, the activity of the i th component) to the liquid phase fraction of a liquid mixture, some of the effects of the real solution can be accounted for. The activity of a real chemical is a function of the thermodynamic state of the system, i.e. temperature and pressure.

  4. NTU method - Wikipedia

    en.wikipedia.org/wiki/NTU_Method

    The number of transfer units (NTU) method is used to calculate the rate of heat transfer in heat exchangers (especially parallel flow, counter current, and cross-flow exchangers) when there is insufficient information to calculate the log mean temperature difference (LMTD). Alternatively, this method is useful for determining the expected heat ...

  5. Fudge factor - Wikipedia

    en.wikipedia.org/wiki/Fudge_factor

    A fudge factor is an ad hoc quantity or element introduced into a calculation, formula or model in order to make it fit observations or expectations. Also known as a correction coefficient , which is defined by

  6. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    This graph is called the "Van 't Hoff plot" and is widely used to estimate the enthalpy and entropy of a chemical reaction. From this plot, − ⁠ Δ r H / R ⁠ is the slope, and ⁠ Δ r S / R ⁠ is the intercept of the linear fit.

  7. Volume correction factor - Wikipedia

    en.wikipedia.org/wiki/Volume_Correction_Factor

    That is, observed temperatures above 60 °F (or the base temperature used) typically correlate with a correction factor below "1", while temperatures below 60 °F correlate with a factor above "1". This concept lies in the basis for the kinetic theory of matter and thermal expansion of matter , which states as the temperature of a substance ...

  8. Chilton and Colburn J-factor analogy - Wikipedia

    en.wikipedia.org/wiki/Chilton_and_Colburn_J...

    Chilton–Colburn J-factor analogy (also known as the modified Reynolds analogy [1]) is a successful and widely used analogy between heat, momentum, and mass transfer.The basic mechanisms and mathematics of heat, mass, and momentum transport are essentially the same.

  9. Schottky effect - Wikipedia

    en.wikipedia.org/wiki/Schottky_effect

    where J is the emission current density, T is the temperature of the metal, W is the work function of the metal, k is the Boltzmann constant, q e is the Elementary charge, ε 0 is the vacuum permittivity, and A G is the product of a universal constant A 0 multiplied by a material-specific correction factor λ R which is typically of order 0.5.