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  2. Critical point (mathematics) - Wikipedia

    en.wikipedia.org/wiki/Critical_point_(mathematics)

    A critical point of a function of a single real variable, f (x), is a value x 0 in the domain of f where f is not differentiable or its derivative is 0 (i.e. ′ =). [2] A critical value is the image under f of a critical point.

  3. Critical point (thermodynamics) - Wikipedia

    en.wikipedia.org/wiki/Critical_point...

    A plot of typical polymer solution phase behavior including two critical points: a LCST and an UCST. The liquid–liquid critical point of a solution, which occurs at the critical solution temperature, occurs at the limit of the two-phase region of the phase diagram. In other words, it is the point at which an infinitesimal change in some ...

  4. Van der Waals equation - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_equation

    This fold develops from a critical point defined by specific values of pressure, temperature, and molar volume. Because the surface is plotted using dimensionless variables (formed by the ratio of each property to its respective critical value), the critical point is located at the coordinates (,,). When drawn using these dimensionless axes ...

  5. Critical variable - Wikipedia

    en.wikipedia.org/wiki/Critical_variable

    Critical variables are defined, for example in thermodynamics, in terms of the values of variables at the critical point. On a PV diagram, the critical point is an inflection point . Thus: [ 1 ]

  6. Second partial derivative test - Wikipedia

    en.wikipedia.org/wiki/Second_partial_derivative_test

    At the remaining critical point (0, 0) the second derivative test is insufficient, and one must use higher order tests or other tools to determine the behavior of the function at this point. (In fact, one can show that f takes both positive and negative values in small neighborhoods around (0, 0) and so this point is a saddle point of f .)

  7. Critical point - Wikipedia

    en.wikipedia.org/wiki/Critical_point

    Critical point (set theory), an elementary embedding of a transitive class into another transitive class which is the smallest ordinal which is not mapped to itself; Critical point (thermodynamics), a temperature and pressure of a material beyond which there is no longer any difference between the liquid and gas phases; Quantum critical point ...

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  9. Saddle point - Wikipedia

    en.wikipedia.org/wiki/Saddle_point

    A saddle point (in red) on the graph of z = x 2 − y 2 (hyperbolic paraboloid). In mathematics, a saddle point or minimax point [1] is a point on the surface of the graph of a function where the slopes (derivatives) in orthogonal directions are all zero (a critical point), but which is not a local extremum of the function. [2]