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For these and similar reasons, the use of aluminium chloride has often been displaced by zeolites. [7] Aluminium chloride can also be used to introduce aldehyde groups onto aromatic rings, for example via the Gattermann-Koch reaction which uses carbon monoxide, hydrogen chloride and a copper(I) chloride co-catalyst. [19]
Aluminum warrants special mention because it is the most abundant metal and the third most abundant element in the Earth's crust; [3] despite this, it is not essential for life. With this sole exception, the eight most highly abundant elements in the Earth's crust , making up over 90% of the crustal mass, [ 3 ] are also essential for life.
Aluminium has a high chemical affinity to oxygen, which renders it suitable for use as a reducing agent in the thermite reaction. A fine powder of aluminium reacts explosively on contact with liquid oxygen ; under normal conditions, however, aluminium forms a thin oxide layer that protects the metal from further corrosion by oxygen, water, or ...
The variation most commonly used in deodorants and antiperspirants is Al 2 Cl(OH) 5 (dialuminium chloride pentahydroxide). Aluminium chlorohydrate is also used as a coagulant in water and wastewater treatment processes to remove dissolved organic matter and colloidal particles present in suspension.
Anhydrous aluminium chloride is used as a catalyst in chemical and petrochemical industries, the dyeing industry, and in synthesis of various inorganic and organic compounds. [166] Aluminium hydroxychlorides are used in purifying water, in the paper industry, and as antiperspirants. [166]
Alum was the most common mordant (substance used to set dyes on fabrics) used by the dye industry, especially in Islamic countries, during the middle ages. It was the main export of the Chad region, from where it was transported to the markets of Egypt and Morocco , and then to Europe .
Tetrachloroaluminate [AlCl 4] − is an anion formed from aluminium and chlorine.The anion has a tetrahedral shape and is isoelectronic with silicon tetrachloride.Some tetrachloroaluminates are soluble in organic solvents, creating an ionic non-aqueous solution, making them suitable as component of electrolytes for batteries.
ORNL used an ionic electrolyte, instead of the typical aqueous electrolyte which can produce hydrogen gas and corrode the anode. The electrolyte was made of 3-ethyl-1-methylimidazolium chloride with excess aluminium trichloride. [23] However, ionic electrolytes are less conductive, reducing power density.