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Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
Rigid boundary – not allowing exchange of work: A mechanically isolated system One example is fluid being compressed by a piston in a cylinder. Another example of a closed system is a bomb calorimeter , a type of constant-volume calorimeter used in measuring the heat of combustion of a particular reaction.
Boundary-work is part of science studies. In boundary-work, boundaries, demarcations, or other divisions between fields of knowledge are created, advocated, attacked, or reinforced. Such delineations often have high stakes for the participants, [1] and carry the implication that such boundaries are flexible and socially constructed. [citation ...
Work and heat are not thermodynamic properties, but rather process quantities: flows of energy across a system boundary. Systems do not contain work, but can perform work, and likewise, in formal thermodynamics, systems do not contain heat, but can transfer heat.
where denotes the change in the internal energy of a closed system (for which heat or work through the system boundary are possible, but matter transfer is not possible), denotes the quantity of energy supplied to the system as heat, and denotes the amount of thermodynamic work done by the system on its surroundings.
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
In thermal equilibrium, each phase (i.e. liquid, solid etc.) of physical matter comes to an end at a transitional point, or spatial interface, called a phase boundary, due to the immiscibility of the matter with the matter on the other side of the boundary. This immiscibility is due to at least one difference between the two substances ...
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125