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Arsenate readily reacts with metals to form arsenate metal compounds. [2] [3] Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. [4] Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with ...
Arsenate (+5 oxidation state) is the dominant form of arsenic in surface water, while arsenite (+3 oxidation state) is the dominant form in hypoxic to anoxic environments. Arsenite is more soluble and mobile than arsenate. Many species of bacteria can transform arsenite to arsenate in anoxic conditions by using arsenite as an electron donor. [189]
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
Ⓘ The p-block shows a relatively distinct cutoff in periods 1 to 4 between elements commonly recognised as metals and nonmetals. Periods 5 and 6 include elements commonly recognised as metalloids by authors who recognise such a class or subclass (antimony and tellurium), and elements less commonly recognised as such (polonium and astatine). [19]
The solubility product was determined to be 10 −18.06 for aluminium arsenate hydrate of formula AlAsO 4 ·3.5H 2 O. [1] Like gallium arsenate and boron arsenate, it adopts the α-quartz-type structure. The high pressure form has a rutile-type structure in which aluminium and arsenic are six-coordinate.
In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many stoichiometries, and in this respect arsenides are similar to phosphides. [1]
Silver arsenate is an inorganic compound with the formula Ag 3 AsO 4. [3] It has been used in qualitative analysis to distinguish between phosphate (Ag 3 PO 4 is yellow) and arsenate(V) solutions. [ 4 ]
A chemical element, often simply called an element, is a type of atom which has a specific number of protons in its atomic nucleus (i.e., a specific atomic number, or Z). [ 1 ] The definitive visualisation of all 118 elements is the periodic table of the elements , whose history along the principles of the periodic law was one of the founding ...