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  2. Sodium dichromate - Wikipedia

    en.wikipedia.org/wiki/Sodium_dichromate

    Sodium dichromate is the inorganic compound with the formula Na 2 Cr 2 O 7. However, the salt is usually handled as its dihydrate Na 2 Cr 2 O 7 ·2 H 2 O . Virtually all chromium ore is processed via conversion to sodium dichromate and virtually all compounds and materials based on chromium are prepared from this salt. [ 1 ]

  3. Jones oxidation - Wikipedia

    en.wikipedia.org/wiki/Jones_oxidation

    The reaction stoichiometry implicates the Cr(IV) species "CrO 2 OH −", which comproportionates with the chromic acid to give a Cr(V) oxide, which also functions as an oxidant for the alcohol. [ 6 ] The oxidation of the aldehydes is proposed to proceed via the formation of hemiacetal -like intermediates, which arise from the addition of the O ...

  4. Alcohol oxidation - Wikipedia

    en.wikipedia.org/wiki/Alcohol_oxidation

    Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.

  5. Oxidation with chromium(VI) complexes - Wikipedia

    en.wikipedia.org/wiki/Oxidation_with_chromium(VI...

    Enones can be synthesized from tertiary allylic alcohols through the action of a variety of chromium(VI)-amine reagents, in a reaction known as the Babler oxidation. The reaction is driven by the formation of a more substituted double bond. (E)-Enones form in greater amounts than (Z) isomers because of chromium-mediated geometric isomerization ...

  6. Black snake (firework) - Wikipedia

    en.wikipedia.org/wiki/Black_snake_(firework)

    Solid fuel is used in this experiment. The solid fuel can be sand that is sufficiently covered in ethanol or hexamethylenetetramine. A white mixture of sucrose and sodium bicarbonate will eventually turn black and the snake will grow about 15–50 centimetres (5.9–19.7 in) long after it is lit. [4] Three chemical reactions occur when the ...

  7. Passivation (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Passivation_(chemistry)

    Sodium dichromate is often required as an additive to oxidise the chromium in certain 'types' of nitric-based acid baths, however this chemical is highly toxic. With citric acid, simply rinsing and drying the part and allowing the air to oxidise it, or in some cases the application of other chemicals, is used to perform the passivation of the ...

  8. Liesegang rings - Wikipedia

    en.wikipedia.org/wiki/Liesegang_rings

    The reactions are most usually carried out in test tubes into which a gel is formed that contains a dilute solution of one of the reactants.. If a hot solution of agar gel also containing a dilute solution of potassium dichromate is poured in a test tube, and after the gel solidifies a more concentrated solution of silver nitrate is poured on top of the gel, the silver nitrate will begin to ...

  9. Bouveault–Blanc reduction - Wikipedia

    en.wikipedia.org/wiki/Bouveault–Blanc_reduction

    Sodium metal is a one-electron reducing agent. Four equivalents of sodium are required to fully reduce each ester, although two more equivalents are typically consumed in deprotonating the product alcohols to alkoxides. Ethanol serves as a proton source. [1] The reaction produces sodium alkoxides, according to the following stoichiometry:

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