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Copper–chlorine cycle. The copper – chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius. [1]
The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde in the presence of palladium (II) chloride and copper (II) chloride as the catalyst. [1] This chemical reaction was one of the first homogeneous catalysis with organopalladium chemistry ...
Copper (II) chloride is used as a catalyst in a variety of processes that produce chlorine by oxychlorination. The Deacon process takes place at about 400 to 450 °C in the presence of a copper chloride: [8] 4 HCl + O2 → 2 Cl2 + 2 H2O. Copper (II) chloride catalyzes the chlorination in the production of vinyl chloride and dichloromethane.
The ionic equation for this reaction is as follows: [10] 3 Cl 2 + 6 OH − → 5 Cl − + ClO − 3 + 3 H 2 O The chlorine reactant is in oxidation state 0. In the products, the chlorine in the Cl − ion has an oxidation number of −1, having been reduced, whereas the oxidation number of the chlorine in the ClO − 3 ion is +5, indicating ...
The most common chloralkali process involves the electrolysis of aqueous sodium chloride (a brine) in a membrane cell. A membrane, such as one made from Nafion, Flemion or Aciplex, is used to prevent the reaction between the chlorine and hydroxide ions. Basic membrane cell used in the electrolysis of brine. At the anode (A), chloride (Cl − ...
Deacon process. The Deacon process, invented by Henry Deacon, is a process used during the manufacture of alkalis (the initial end product was sodium carbonate) by the Leblanc process. Hydrogen chloride gas was converted to chlorine gas, which was then used to manufacture a commercially valuable bleaching powder, and at the same time the ...
IR absorption spectrum of copper (I) chloride. Copper (I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear green due to the presence of copper (II) chloride (CuCl 2).
Transition metal chloride complex. Octahedral molecular geometry is a common structural motif for homoleptic metal chloride complexes. Examples include MCl 6 (M = Mo, W), [MCl 6] − (M = Nb, Ta, Mo, W, Re), [MCl 6] 2- (M = Ti Zr, Hf, Mo, Mn, Re, Ir, Pd, Pt), and [MCl 6] 3- (M = Ru Os, Rh, Ir). In chemistry, a transition metal chloride complex ...