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A quantum number beginning in n = 3,ℓ = 0, describes an electron in the s orbital of the third electron shell of an atom. In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of ...
The associated quantum number is the main total angular momentum quantum number j. It can take the following range of values, jumping only in integer steps: [ 1 ] | ℓ − s | ≤ j ≤ ℓ + s {\displaystyle \vert \ell -s\vert \leq j\leq \ell +s} where ℓ is the azimuthal quantum number (parameterizing the orbital angular momentum) and s is ...
s = spin quantum number; m s = spin magnetic quantum number; ℓ = Azimuthal quantum number; m ℓ = azimuthal magnetic quantum number; j = total angular momentum quantum number; m j = total angular momentum magnetic quantum number
The four quantum numbers n, ℓ, m, and s specify the complete and unique quantum state of a single electron in an atom, called its wave function or orbital. Two electrons belonging to the same atom cannot have the same values for all four quantum numbers, due to the Pauli exclusion principle .
The quantum numbers corresponding to these operators are , , (always 1/2 for an electron) and respectively. The energy levels in the hydrogen atom depend only on the principal quantum number n . For a given n , all the states corresponding to ℓ = 0 , … , n − 1 {\displaystyle \ell =0,\ldots ,n-1} have the same energy and are degenerate.
The phrase spin quantum number refers to quantized spin angular momentum. The symbol s is used for the spin quantum number, and m s is described as the spin magnetic quantum number [3] or as the z-component of spin s z. [4] Both the total spin and the z-component of spin are quantized, leading to two quantum numbers spin and spin magnet quantum ...
The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment
However the multiplicity equals the number of spin orientations only if S ≤ L. When S > L there are only 2L+1 orientations of total angular momentum possible, ranging from S+L to S-L. [ 2 ] [ 3 ] The ground state of the nitrogen atom is a 4 S state, for which 2S + 1 = 4 in a quartet state, S = 3/2 due to three unpaired electrons.