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Rust bluing was developed between hot and cold bluing processes, and was originally used by gunsmiths in the 19th century to blue firearms prior to the development of hot bluing processes. The process was to coat the gun parts in an acid solution, let the parts rust uniformly, then immerse the parts in boiling water to convert the red oxide Fe 2 O
The NaOH (caustic soda) and elevated temperature cause Fe 3 O 4 (black oxide) to form on the surface of the metal instead of Fe 2 O 3 (red oxide; rust). While it is physically denser than red oxide, the fresh black oxide is porous, so oil is then applied as post treatment to the heated part, which seals it by "sinking" into it.
Lunar caustic/ lapis infernalis – silver nitrate, formed by dissolving silver in aqua fortis and evaporating. Lye – potash in a water solution, formed by leaching wood ashes. Potash – potassium carbonate, formed by evaporating lye; also called salt of tartar. K 2 CO 3; Pearlash – formed by baking potash in a kiln.
Black oxide is but one type of bluing for firearms; there are other types of bluing used on firearms, too. (Hot bluing vs. cold bluing, and hot bluing versus "hot and cold" mixed bluing, for example.) Black oxide is also used to refer to thicker bluing that is black oxide based.
Bluing (steel) is a passivation process in which steel is partially protected against rust Bluing may also refer to: Bluing (fabric), a blue dye used to improve the appearance of fabrics; Bluing (hair), a blue dye used to improve the appearance of hair "bluing" of machine parts to check for tolerances, see engineer's blue
Phosphate conversion coating is a chemical treatment applied to steel parts that creates a thin adhering layer of iron, zinc, or manganese phosphates to improve corrosion resistance or lubrication or as a foundation for subsequent coatings or painting.
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