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In organic chemistry, a ketone / ˈ k iː t oʊ n / is an organic compound with the structure R−C(=O)−R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group −C(=O)− (a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' are methyl), with the formula (CH 3) 2 CO ...
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If a prefix form is required, "oxo-" is used (as for ketones), with the position number indicating the end of a chain: CHOCH 2 COOH is 3-oxopropanoic acid. If the carbon in the carbonyl group cannot be included in the attached chain (for instance in the case of cyclic aldehydes ), the prefix "formyl-" or the suffix "-carbaldehyde" is used: C 6 ...
The Buchner–Curtius–Schlotterbeck reaction is the reaction of aldehydes or ketones with aliphatic diazoalkanes to form homologated ketones. [1] It was first described by Eduard Buchner and Theodor Curtius in 1885 [2] and later by Fritz Schlotterbeck in 1907. [3]
Fructose, an example of a ketose. The ketone group is the double-bonded oxygen. In organic chemistry, a ketose is a monosaccharide containing one ketone (>C=O) group per molecule. [1] [2] The simplest ketose is dihydroxyacetone ((CH 2 OH) 2 C=O), which has only three carbon atoms. It is the only ketose with no optical activity.
General chemical structure of a polyketone. Polyketones are a family of high-performance thermoplastic polymers. The polar ketone groups in the polymer backbone of these materials gives rise to a strong attraction between polymer chains, which increases the material's melting point (255 °C for copolymer (carbon monoxide ethylene), 220 °C for terpolymer (carbon monoxide, ethylene, propylene).
However, in order for anomers to exist, the sugar must be in its cyclic form, since in open-chain form, the anomeric carbon atom is planar and thus achiral. More formally stated, then, an anomer is an epimer at the hemiacetal/hemiketal carbon atom in a cyclic saccharide. [1] Anomerization is the process of conversion of one anomer to the other.
Examples of homologation reactions include: Kiliani-Fischer synthesis, where an aldose molecule is elongated through a three-step process consisting of: Nucleophillic addition of cyanide to the carbonyl to form a cyanohydrin; Hydrolysis to form a lactone; Reduction to form the homologous aldose