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Sodium bisulfate is produced as an intermediate in the Mannheim process, an industrial process involving the reaction of sodium chloride and sulfuric acid: [1] NaCl + H 2 SO 4 → HCl + NaHSO 4. The process for the formation of sodium bisulfate is highly exothermic. The liquid sodium bisulfate is sprayed and cooled so that it forms a solid bead.
Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO 3. Sodium bisulfite is not a real compound, [ 2 ] but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions.
This clock reaction uses sodium, potassium or ammonium persulfate to oxidize iodide ions to iodine. Sodium thiosulfate is used to reduce iodine back to iodide before the iodine can complex with the starch to form the characteristic blue-black color. Iodine is generated: 2 I − + S 2 O 2− 8 → I 2 + 2 SO 2− 4. And is then removed:
The Mannheim process is an industrial process for the production of hydrogen chloride and sodium sulfate from sulfuric acid and sodium chloride. [1] The Mannheim furnace is also used to produce potassium sulfate from potassium chloride. [2] The Mannheim process is a stage in the Leblanc process for the production of sodium carbonate.
This, along with the ability of the kraft process to accept a wider variety of types of wood and produce stronger fibers [4] made the kraft process the dominant pulping process starting in the 1940s. [3] Sulfite pulps now account for less than 10% of the total chemical pulp production [3] and the number of sulfite mills continues to decrease ...
The Wellman–Lord process is a regenerable process to remove sulfur dioxide from flue gas (flue-gas desulfurization) without creating a throwaway sludge product.. In this process, sulfur dioxide from flue gas is absorbed in a sodium sulfite solution in water forming sodium bisulfite; other components of flue gas are not absorbed.
The most important chemical sodium sulfate production is during hydrochloric acid production, either from sodium chloride (salt) and sulfuric acid, in the Mannheim process, or from sulfur dioxide in the Hargreaves process. [21] The resulting sodium sulfate from these processes is known as salt cake. Mannheim: 2 NaCl + H 2 SO 4 → 2 HCl + Na 2 SO 4
Chemical pulping involves dissolving lignin in order to extract the cellulose from the wood fiber. The different processes of chemical pulping include the Kraft process, which uses caustic soda and sodium sulfide and is the most common; alternatively, the use of sulfurous acid is known as the sulfite process, the neutral sulfite semichemical is treated as a third process separate from sulfite ...