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Electrogalvanizing is a process in which a layer of zinc is bonded to steel to protect against corrosion, enhance adhesion, or give an aesthetic appeal.The process involves electroplating, running a current of electricity through a saline-/zinc-based electrolytic solution with a zinc anode and steel cathode.
The electrolyte in the electrolytic plating cell should contain positive ions (cations) of the metal to be deposited. These cations are reduced at the cathode to the metal in the zero valence state. For example, the electrolyte for copper electroplating can be a solution of copper(II) sulfate, which dissociates into Cu 2+ cations and SO 2− 4 ...
Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for ...
The difference can be measured as a difference in voltage potential: the less noble metal is the one with a lower (that is, more negative) electrode potential than the nobler one, and will function as the anode (electron or anion attractor) within the electrolyte device functioning as described above (a galvanic cell).
Immersion zinc plating is an electroless (non-electrolytic) coating process that deposits a thin layer of zinc on a less electronegative metal, by immersion in a solution containing a zinc or zincate ions, Zn(OH) 2− 4. A typical use is plating aluminum with zinc prior to electrolytic or electroless nickel plating.
The electrolyte is a (saturated) solution of cadmium sulfate. The depolarizer is a paste of mercurous sulfate. When the electrolyte solution is saturated, the voltage of the cell is very reproducible; hence, in 1911, it was adopted as an international standard for voltage.
As a simple electrolyte, it is possible to use a 3% solution of trisodium phosphate, a cathode of stainless steel, object as anode. The color depends on voltage. Many other electrolytes can be used—even Coca-Cola. Straw yellow / 10V – violet / 29 V – blue / 30 V – blue green 45 V – light green / 55 V – purple-red / 75 V – grey ...
Zinc is rarely anodized, but a process was developed by the International Lead Zinc Research Organization and covered by MIL-A-81801. [17] A solution of ammonium phosphate, chromate and fluoride with voltages of up to 200 V can produce olive green coatings up to 80 μm thick. [17] The coatings are hard and corrosion resistant.