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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
For example, if narrow molar mass distribution standards are available for polystyrene, these can be used to construct a calibration curve (typically vs. retention volume ) in eg. toluene at 40 °C. This calibration can then be used to determine the "polystyrene equivalent" molecular weight of a polyethylene sample if the Mark-Houwink ...
The calibration curve that does not use the internal standard method ignores the uncertainty between measurements. The coefficient of determination (R 2) for this plot is 0.9985. In the calibration curve that uses the internal standard, the y-axis is the ratio of the nickel signal to the yttrium signal.
Using the calibration curve method, the analyst can calibrate the spectrometer with a pure silver aqueous solutions, and use the calibration graph to determine the amount of silver present in the waste samples. This method, however, assumes the pure aqueous solution of silver and a photographic waste sample have the same matrix and therefore ...
An example of a Levey–Jennings chart with upper and lower limits of one and two times the standard deviation. A Levey–Jennings chart is a graph that quality control data is plotted on to give a visual indication whether a laboratory test is working well.
There are two main uses of the term calibration in statistics that denote special types of statistical inference problems. Calibration can mean a reverse process to regression, where instead of a future dependent variable being predicted from known explanatory variables, a known observation of the dependent variables is used to predict a corresponding explanatory variable; [1]
The equation of a line on a linear–log plot, where the abscissa axis is scaled logarithmically (with a logarithmic base of n), would be = +. The equation for a line on a log–linear plot, with an ordinate axis logarithmically scaled (with a logarithmic base of n), would be:
Although "International Temperature Scale of 1990" has the word "scale" in its title, this is a misnomer that can be misleading. The ITS-90 is not a scale; it is an equipment calibration standard. Temperatures measured with equipment calibrated per ITS-90 may be expressed using any temperature scale such as Celsius, Kelvin, Fahrenheit, or Rankine.