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Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition.Polymers and particularly plastics are subject to degradation at all stages of their product life cycle, including during their initial processing, use, disposal into the environment and recycling. [1]
A plastic is considered a bioplastic if it was produced partly or wholly with biologically sourced polymers. A plastic is considered biodegradable if it can degrade into water, carbon dioxide, and biomass in a given time frame (dependent on different standards). Thus, the terms are not synonymous. Not all bioplastics are biodegradable. [44]
Plastarch Material (PSM) is a biodegradable, thermoplastic resin. It is composed of starch combined with several other biodegradable materials. The starch is modified in order to obtain heat-resistant properties, making PSM one of few bioplastics capable of withstanding high temperatures.
Furthermore, plastic bottles and plastic bags that end up in landfills are frequently consumed by animals, which then clogs their digestive systems and leads to death. [4] Because of the substantial growth in plastic consumption, biodegradable additives are becomingly increasingly necessary to increase the rate of degradability of common plastics.
However, bioplastics in soil environments need higher temperatures and a longer time to biodegrade. [73] Some bioplastics biodegrade more efficiently in water bodies and marine systems; however, this causes danger to marine ecosystems and freshwater. [ 73 ]
This plastic bucket has been used as an open-air flowerpot for some years. Photodegradation has made it brittle, causing part of it to break off when the bucket was moved. In polymer chemistry, photo-oxidation (sometimes: oxidative photodegradation) is the degradation of a polymer surface due to the combined action of light and oxygen. [1]
The energy of the propagating crack is then transferred to the rubber particles along its path. A large number of cracks give the originally rigid material a laminated structure. The formation of each lamella contributes to the consumption of energy and thus to an increase in elongation at break.
Plastic recycling improves usage of resources. Biodegradable films need to be kept away from the usual recycling stream to prevent contaminating the polymers to be recycled. If disposed of in a sanitary landfill, most traditional plastics do not readily decompose. The conditions of a sealed landfill additionally deter degradation of ...