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Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Because aggressive bases like KOH damage the cuticle of the hair shaft, potassium hydroxide is used to chemically assist the removal of hair from animal hides. The hides are soaked for several hours in a solution of KOH and water to prepare them for the unhairing stage of the tanning process. This same effect is also used to weaken human hair ...
The reaction between sodium hydroxide and some metals is also hazardous. Aluminium, magnesium, zinc, tin, chromium, brass and bronze all react with lye to produce hydrogen gas. Since hydrogen is flammable, mixing a large quantity of lye with aluminium could result in an explosion. Both the potassium and sodium forms are able to dissolve copper.
Alkaline water electrolysis is a type of electrolysis that is characterized by having two electrodes operating in a liquid alkaline electrolyte. Commonly, a solution of potassium hydroxide (KOH) or sodium hydroxide (NaOH) at 25-40 wt% is used. [ 6 ]
After completion of the reaction, water is added, and the remaining unreacted acetic anhydride is converted to acetic acid and measured by titration with potassium hydroxide. The hydroxyl value can be calculated using the following equation.
The hydroxide ion is naturally produced from water by the self-ionization reaction: [2] H 3 O + + OH − ⇌ 2H 2 O. The equilibrium constant for this reaction, defined as K w = [H +][OH −] [note 1] has a value close to 10 −14 at 25 °C, so the concentration of hydroxide ions in pure water is close to 10 −7 mol∙dm −3, to