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Chloroethane is produced by hydrochlorination of ethylene: [11]. C 2 H 4 + HCl → C 2 H 5 Cl. At various times in the past, chloroethane has also been produced from ethanol and hydrochloric acid, from ethane and chlorine, or from ethanol and phosphorus trichloride, but these routes are no longer economical.
In the laboratory it is occasionally used as a source of chlorine, with elimination of ethene and chloride. Via several steps, 1,2-dichloroethane is a precursor to 1,1,1-trichloroethane . Historically, before leaded petrol was phased out, chloroethanes were used as an additive in petrol to prevent lead buildup in engines.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The levelized cost of water (LCOW or LCW) is the "cost per unit volume of product water produced by a water treatment process or service". It is a measure of efficiency, with lower values representing more efficient methods. LCW can refer to drinking water for human consumption or water for irrigation. [1]
A dealkalizer contains strong base anion exchange resin that exchanges chloride (the Cl – ion of the NaCl) for carbonate (CO − 3), bicarbonate (H C O − 3) and sulfate (SO 2− 4). As water passes through the anion resin the carbonate, bicarbonate and sulfate ions are exchanged for chloride ions.
Depending on the effluent nature, an increase of the conductivity of the solution may be required: the value of 1000 mS/cm is commonly taken as a threshold. [13] Salts like sodium chloride or sodium sulfate can be added to the solution, acting as electrolytes, thus raising the conductivity. Typical values of salts concentration are in the range ...
The 1,1,2,2-tetrachloroethane is then dehydrochlorinated to give trichloroethylene. This can be accomplished either with an aqueous solution of calcium hydroxide: 2 Cl 2 CHCHCl 2 + Ca(OH) 2 → 2 ClCH=CCl 2 + CaCl 2 + 2 H 2 O. or in the vapor phase by heating it to 300–500 °C on a barium chloride or calcium chloride catalyst: Cl 2 CHCHCl 2 ...
In oxychlorination, hydrogen chloride instead of the more expensive chlorine is used for the same purpose: CH 2 =CH 2 + 2 HCl + 1 ⁄ 2 O 2 → ClCH 2 CH 2 Cl + H 2 O. Secondary and tertiary alcohols react with hydrogen chloride to give the corresponding chlorides. In the laboratory, the related reaction involving zinc chloride in concentrated ...