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In thermodynamics, an isochoric process, also called a constant-volume process, an isovolumetric process, or an isometric process, is a thermodynamic process during which the volume of the closed system undergoing such a process remains constant. An isochoric process is exemplified by the heating or the cooling of the contents of a sealed ...
The two independent theories address the physical phenomena of light and matter. In 1905, Albert Einstein argued that the requirement of consistency between thermodynamics and electromagnetism [3] leads to the conclusion that light is quantized, obtaining the relation =. This paper is the dawn of quantum theory.
Photoexcitation is the first step in a photochemical process where the reactant is elevated to a state of higher energy, an excited state.The first law of photochemistry, known as the Grotthuss–Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place.
However, the intensity of light drops rapidly with the distance to the light source due to adsorption by the reactants. [12] The influence of the radiation on the reaction rate can often be represented by a power law based on the quantum flow density, i.e. the mole light quantum (previously measured in the unit einstein) per area and time. One ...
Quantum optics is a branch of atomic, molecular, and optical physics and quantum chemistry dealing with how individual quanta of light, known as photons, interact with atoms and molecules. It includes the study of the particle-like properties of photons.
Isochoric may refer to: cell-transitive, in geometry; isochoric process, a constant volume process in chemistry or thermodynamics; Isochoric model
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments. [1]
The second law determines whether a proposed physical or chemical process is forbidden or may occur spontaneously. For isolated systems, no energy is provided by the surroundings and the second law requires that the entropy of the system alone must increase: ΔS > 0. Examples of spontaneous physical processes in isolated systems include the ...