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  2. Bouveault–Blanc reduction - Wikipedia

    en.wikipedia.org/wiki/Bouveault–Blanc_reduction

    In practice, considerable sodium is consumed by the formation of hydrogen. [citation needed] For this reason, an excess of sodium is often required. Because the hydrolysis of sodium is rapid, not to mention dangerous, the Bouveault-Blanc reaction requires anhydrous ethanol and can give low yields with insufficiently dry ethanol.

  3. Methanol toxicity - Wikipedia

    en.wikipedia.org/wiki/Methanol_toxicity

    Alcohol dehydrogenase instead enzymatically converts ethanol to acetaldehyde, a less toxic organic molecule. [15] [20] Additional treatment may include sodium bicarbonate for metabolic acidosis, and hemodialysis or hemodiafiltration to remove methanol and formate from the blood. [15]

  4. Alcohol oxidation - Wikipedia

    en.wikipedia.org/wiki/Alcohol_oxidation

    Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.

  5. Cannizzaro reaction - Wikipedia

    en.wikipedia.org/wiki/Cannizzaro_reaction

    Under ideal conditions the reaction produces 50% of both the alcohol and the carboxylic acid (it takes two aldehydes to produce one acid and one alcohol). [5] This can be economically viable if the products can be separated and both have a value; the commercial conversion of furfural into furfuryl alcohol and 2-furoic acid is an example of this ...

  6. Fétizon oxidation - Wikipedia

    en.wikipedia.org/wiki/Fétizon_oxidation

    The solvent is also typically refluxed to drive the reaction with heat and remove the water generated by the reaction through azeotropic distillation. Steric hindrance of the hydrogen alpha to the alcohol is a major determination of the rate of oxidation as it affects the rate of association. [5]

  7. Sodium oxybate - Wikipedia

    en.wikipedia.org/wiki/Sodium_oxybate

    The US label for sodium oxybate has a black box warning because it is a central nervous system depressant (CNS depressant) and for its potential for abuse.Other potential adverse side effects include respiratory depression, seizures, coma, and death, especially when it is taken in combination with other CNS depressants such as alcohol.

  8. Finkelstein reaction - Wikipedia

    en.wikipedia.org/wiki/Finkelstein_reaction

    The classic Finkelstein reaction entails the conversion of an alkyl chloride or an alkyl bromide to an alkyl iodide by treatment with a solution of sodium iodide in acetone. Sodium iodide is soluble in acetone while sodium chloride and sodium bromide are not; [ 3 ] therefore, the reaction is driven toward products by mass action due to the ...

  9. Favorskii reaction - Wikipedia

    en.wikipedia.org/wiki/Favorskii_reaction

    The reaction was discovered in the early 1900s by the Russian chemist Alexei Yevgrafovich Favorskii. [1] Favorskii reaction and the possible subsequent rearrangement. When the carbonyl is an aldehyde (R"=H), a rearrangement can occur to generate enone, although the secondary propargylic alcohol can be isolated in some cases. [2]

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