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The bond energy for H 2 O is the average energy required to break each of the two O–H bonds in sequence: Although the two bonds are the equivalent in the original symmetric molecule, the bond-dissociation energy of an oxygen–hydrogen bond varies slightly depending on whether or not there is another hydrogen atom bonded to the oxygen atom.
By Landauer's principle, the minimum amount of energy required at 25 °C to change one bit of information 3–7×10 −21 J Energy of a van der Waals interaction between atoms (0.02–0.04 eV) [11] [12] 4.1×10 −21 J The "kT" constant at 25 °C, a common rough approximation for the total thermal energy of each molecule in a system (0.03 eV) [13]
Bond energies and bond-dissociation energies are typically in the range of a few eV per bond. The bond-dissociation energy of a carbon-carbon bond is about 3.6 eV. Molecular level: Electron binding energy; Ionization energy Electron binding energy, more commonly known as ionization energy, [3] is a measure of the energy required to free an ...
The geometric mean is approximately equal to the arithmetic mean—which is applied in the first formula above—when the energies are of a similar value, e.g., except for the highly electropositive elements, where there is a larger difference of two dissociation energies; the geometric mean is more accurate and almost always gives positive ...
The bond-dissociation energy of a bond is the amount of energy required to cleave the bond homolytically. This enthalpy change is one measure of bond strength . The triplet excitation energy of a sigma bond is the energy required for homolytic dissociation, but the actual excitation energy may be higher than the bond-dissociation energy due to ...
The enthalpy of fusion is the amount of energy required to convert one mole of solid into liquid. For example, when melting 1 kg of ice (at 0 °C under a wide range of pressures), 333.55 kJ of energy is absorbed with no temperature change. The heat of solidification (when a substance changes from liquid to solid) is equal and opposite.
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The bond dissociation energy is related to but slightly different from the depth of the associated potential energy well of the bond, D e, known as the electronic energy. This is due to the existence of a zero-point energy ε 0 for the vibrational ground state, which reduces the amount of energy needed to reach the dissociation limit.