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Solid-phase electrical conductivity: Variable, [6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopants can exhibit metal-like conductivity.
Graphite (/ ˈ ɡ r æ f aɪ t /) is a crystalline allotrope (form) of the element carbon. It consists of many stacked layers of graphene, typically in the excess of hundreds of layers. Graphite occurs naturally and is the most stable form of carbon under standard conditions.
[1] [2] [3] For example, if a 1 m 3 solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is 1 Ω, then the resistivity of the material is 1 Ω⋅m. Electrical conductivity (or specific conductance) is the reciprocal of electrical resistivity. It represents a material's ability to conduct ...
A network covalent solid consists of atoms held together by a network of covalent bonds (pairs of electrons shared between atoms of similar electronegativity), and hence can be regarded as a single, large molecule. The classic example is diamond; other examples include silicon, [3] quartz and graphite.
Graphite, named by Abraham Gottlob Werner in 1789, from the Greek γράφειν (graphein, "to draw/write", for its use in pencils) is one of the most common allotropes of carbon. Unlike diamond, graphite is an electrical conductor. Thus, it can be used in, for instance, electrical arc lamp electrodes.
Graphite, a 3D counterpart to graphene, exhibits a basal plane thermal conductivity exceeding 1000 W⋅m −1 ⋅K −1 (similar to diamond), In graphite, the c-axis (out of plane) thermal conductivity is over a factor of ~100 smaller due to the weak binding forces between basal planes as well as the larger lattice spacing. [179]
A well-studied example is the radical ion salt TTF-TCNQ with a conductivity of 5 x 10 2 Ω −1 cm −1, [5] much closer to copper (ρ = 6 x 10 5 Ω −1 cm −1) [8] than many molecular solids. [ 31 ] [ 18 ] [ 30 ] The coulombic interaction in TTF-TCNQ stems from the large partial negative charge (δ = -0.59) on the cyano- moiety on TCNQ at ...
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states.