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3-Hydroxylcarbonyls, called aldols, release water upon standing at room temperature: RC(O)CH 2 CH(OH)R' → RC(O)CH=CHR' + H 2 O. The reaction is induced by dehydrating reagents. For example, 2-methyl-cyclohexan-1-ol dehydrates to 1-methylcyclohexene in the presence of Martin's sulfurane, which reacts irreversibly with water. [6] [7]
Isotope fractionation occurs during a phase transition, the ratio of light to heavy isotopes in the involved molecules changes. When water vapor condenses (an equilibrium fractionation), the heavier water isotopes (18 O and 2 H) become enriched in the liquid phase while the lighter isotopes (16 O and 1 H) tend toward the vapor phase. [4]
The exothermic (heat producing) reaction between potassium permanganate (KMnO 4), a strong oxidizing agent, and glycerol (C 3 H 5 (OH) 3), a readily oxidised organic substance, is an example of an experiment sometimes referred to as a "chemical volcano". [7] [8]
A similar concept applies to liquid–gas phase changes. [7] Water is an exception which has a solid-liquid boundary with negative slope so that the melting point decreases with pressure. This occurs because ice (solid water) is less dense than liquid water, as shown by the fact that ice floats on water.
This is an accepted version of this page This is the latest accepted revision, reviewed on 8 September 2024. Term in marketing scam For the water surface phenomenon, see Exclusion zone (physics). For the six-sided shape freezing water takes in nature, see snowflake. Hexagonal water, also known as gel water, structured water, cluster water, H3O2 or H 3 O 2 is a term used in a marketing scam ...
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In drinking water supplies the cause of unacceptable quality can similarly be determined by carefully targeted chemical analysis of samples taken throughout the distribution system. [8] In manufacturing, off-spec products may be directly tied back to unexpected changes in wet processing stages and analytical chemistry can identify which stages ...
In organic chemistry, a hydrate is a compound formed by the hydration, i.e. "Addition of water or of the elements of water (i.e. H and OH) to a molecular entity". [5] For example: ethanol , CH 3 −CH 2 −OH , is the product of the hydration reaction of ethene , CH 2 =CH 2 , formed by the addition of H to one C and OH to the other C, and so ...