Search results
Results From The WOW.Com Content Network
In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound. It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [ 1 ]
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
In organic chemistry, it selectively cleaves ethers and oximes, and couples diarylamines. [5] NOBF 4 is a convenient oxidant because the byproduct NO is a gas, which can be swept from the reaction using a stream of N 2. Upon contact with air, NO forms NO 2, which can cause secondary reactions if it is not removed.
Nitrogen dioxide is a chemical compound with the formula NO 2.One of several nitrogen oxides, nitrogen dioxide is a reddish-brown gas.It is a paramagnetic, bent molecule with C 2v point group symmetry.
For example, Tetracyanoethylene serves as an oxidant due to its attachment to four cyano substituents, which are electron-withdrawing groups. [5] Oxidants with EWGs are stronger than the parent compound. Acetylferrocenium is 300 mV more oxidizing than ferrocene. [citation needed]
Hyperconjugation can be used to rationalize a variety of chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals, and the thermodynamic Zaitsev's rule for alkene stability.
Diazo compounds have two main Lewis structures in resonance: R 2 >C − –N + ≡N and R 2 >CH=N + =N −. In organic chemistry, the diazo group is an organic moiety consisting of two linked nitrogen atoms at the terminal position.
Structural formula of nitroso group. In organic chemistry, nitroso refers to a functional group in which the nitric oxide (−N=O) group is attached to an organic moiety.As such, various nitroso groups can be categorized as C-nitroso compounds (e.g., nitrosoalkanes; R−N=O), S-nitroso compounds (nitrosothiols; RS−N=O), N-nitroso compounds (e.g., nitrosamines, RN(−R’)−N=O), and O ...