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Accordingly, solution polymerization is primarily used in applications where the presence of a solvent is desired anyway, as is the case for varnish and adhesives. Another application of polymer solutions includes the manufacture of fibers by wet or dry spinning or plastic films.
Polymer solutions are used in producing fibers, films, glues, lacquers, paints, and other items made of polymer materials. Thin layers of polymer solution can be used to produce light-emitting devices. [6] Guar polymer solution gels can be used in hydraulic fracturing ("fracking"). [7]
Solvent bonding differs from adhesive bonding, because the solvent does not become a permanent addition to the joined substrate. [4] Solvent bonding differs from other plastic welding processes in that heating energy is generated by the chemical reaction between the solvent and thermoplastic, and cooling occurs during evaporation of the solvent ...
(However, PE only dissolves at temperatures well above 100 °C.) Poly(styrene) has a solubility parameter of 9.1 cal 1/2 cm −3/2, and thus ethyl acetate is likely to be a good solvent. Nylon 6,6 has a solubility parameter of 13.7 cal 1/2 cm −3/2, and ethanol is likely to be the best solvent of those tabulated. However, the latter is polar ...
B reflects the energy of binary interactions between solvent molecules and segments of polymer chain. When B > 0, the solvent is "good," and when B < 0, the solvent is "poor". For a theta solvent, the second virial coefficient is zero because the excess chemical potential is zero; otherwise it would fall outside the definition of a theta solvent.
Crystalline polymers polypropylene and polyethylene display particle strengthening. [28] Plastics are viscoelastic materials meaning that under applied stress, their deformation increases with time (creep). The elastic properties of plastics are therefore distinguished according to the time scale of the testing to short-time behavior (such as ...
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