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A quantum number beginning in n = 3,ℓ = 0, describes an electron in the s orbital of the third electron shell of an atom. In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of ...
The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment
Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms. [2]: 1.1 It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot.
s = spin quantum number; m s = spin magnetic quantum number; ℓ = Azimuthal quantum number; m ℓ = azimuthal magnetic quantum number; j = total angular momentum quantum number; m j = total angular momentum magnetic quantum number
The four quantum numbers n, ℓ, m, and s specify the complete and unique quantum state of a single electron in an atom, called its wave function or orbital. Two electrons belonging to the same atom cannot have the same values for all four quantum numbers, due to the Pauli exclusion principle .
The spin magnetic quantum number m s specifies the z-axis component of the spin angular momentum for a particle having spin quantum number s. For an electron, s is 1 ⁄ 2 , and m s is either + 1 ⁄ 2 or − 1 ⁄ 2 , often called "spin-up" and "spin-down", or α and β.
These are the principal quantum number, the orbital angular momentum quantum number, and the magnetic quantum number. Together with one spin-projection quantum number of the electron, this is a complete set of observables. The figure can serve to illustrate some further properties of the function spaces of wave functions.
A certain number of good quantum numbers can be used to specify uniquely a certain quantum state only when the observables corresponding to the good quantum numbers form a CSCO. If the observables commute, but don't form a CSCO, then their good quantum numbers refer to a set of states. In this case they don't refer to a state uniquely.