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Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, [9] together with yttrium and the lanthanides. It was discovered in 1879 by spectral analysis of the minerals euxenite and gadolinite from Scandinavia. [10]
The reaction of scandium trichloride with two equivalents of sodium cyclopentadienide (NaCp) produces the chloride-bridged dimer: 2 ScCl 3 + 4 NaCp → [Cp 2 Sc(μ-Cl)] 2 + 4 NaCl. Cp 3 Sc is a polymer wherein one third of the Cp ligands serving as bridging ligands. [5] Bulkier cyclopentadienide ligands give monoscandium derivatives, e.g. (C 5 ...
The group is also called the scandium group or scandium family after its lightest member. The chemistry of the group 3 elements is typical for early transition metals: they all essentially have only the group oxidation state of +3 as a major one, and like the preceding main-group metals are quite electropositive and have a less rich ...
Upload file; Search. Search. Appearance. Donate; ... Download QR code; Print/export ... Scandium compounds are compounds that contain the chemical element scandium ...
Scandium acetylacetonate is the coordination complex with the formula Sc(C 5 H 7 O 2) 3 where [C 5 H 7 O 2] − refers to acetylacetonate. It is a volatile white solid that is soluble in benzene. The complex features Sc(III) with octahedral molecular geometry. [1] It was first prepared by treating scandium nitrate with acetylacetone in the ...
The anhydrous form can be produced by the reaction of bromine, scandium oxide and graphite in nitrogen gas. [6] Heating reaction between ammonium bromide and scandium oxide or scandium bromide hexahydrate, through (NH 4) 3 ScBr 6 intermediate, decomposes to obtain anhydrous scandium bromide. [7]
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Aluminium–scandium alloys (AlSc) are aluminum alloys that consist largely of aluminium (Al) and traces of scandium (Sc) as the main alloying elements.In principle, aluminium alloys strengthened with additions of scandium are very similar to traditional nickel-base superalloys in that both are strengthened by coherent, coarsening resistant precipitates with an ordered L1 2 structure.