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The Maxwell–Stefan diffusion (or Stefan–Maxwell diffusion) is a model for describing diffusion in multicomponent systems. The equations that describe these transport processes have been developed independently and in parallel by James Clerk Maxwell [1] for dilute gases and Josef Stefan [2] for liquids. The Maxwell–Stefan equation is [3 ...
Darcy's law is an equation that describes the flow of a fluid through a porous medium and through a Hele-Shaw cell.The law was formulated by Henry Darcy based on results of experiments [1] on the flow of water through beds of sand, forming the basis of hydrogeology, a branch of earth sciences.
In applications to gas dynamics, the diffusion flux and the bulk flow should be joined in one system of transport equations. The bulk flow describes the mass transfer. Its velocity V is the mass average velocity. It is defined through the momentum density and the mass concentrations:
The porous medium equation name originates from its use in describing the flow of an ideal gas in a homogeneous porous medium. [6] We require three equations to completely specify the medium's density , flow velocity field , and pressure : the continuity equation for conservation of mass; Darcy's law for flow in a porous medium; and the ideal gas equation of state.
This diffusion is always a non-equilibrium process, increases the system entropy, and brings the system closer to equilibrium. The diffusion coefficients for these two types of diffusion are generally different because the diffusion coefficient for chemical diffusion is binary and it includes the effects due to the correlation of the movement ...
In particular, experiments on the diffusion of foreign material in a turbulent water stream, [6] vertical structure of water in lake bodies, [7] and lowest part of the atmosphere [8] found experimental evidence that eddy diffusion is indeed stronger than molecular diffusion and generally obeys the theory originally developed by G. I. Taylor ...
When a system contains two or more components whose concentration vary from point to point, there is a natural tendency for mass to be transferred, minimizing any concentration difference within the system. Mass transfer in a system is governed by Fick's first law: 'Diffusion flux from higher concentration to lower concentration is proportional ...
The advection equation is a first-order hyperbolic partial differential equation that governs the motion of a conserved scalar field as it is advected by a known velocity vector field. [1] It is derived using the scalar field's conservation law , together with Gauss's theorem , and taking the infinitesimal limit.