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Ferrocene and its derivatives are antiknock agents added to the petrol used in motor vehicles, and are safer than the now-banned tetraethyllead. [18] Petrol additive solutions containing ferrocene can be added to unleaded petrol to enable its use in vintage cars designed to run on leaded petrol. [19]
The octane rating of gasoline is measured in a test engine and is defined by comparison with the mixture of 2,2,4-trimethylpentane (iso-octane) and normal heptane that would have the same anti-knocking capability as the fuel under test. The percentage, by volume, of 2,2,4-trimethylpentane in that mixture is the octane number of the fuel.
The first number indicates the octane rating of the fuel tested to "aviation lean" standards, which is similar to the anti-knock index or "pump rating" given to automotive gasoline in the US. The second number indicates the octane rating of the fuel tested to the " aviation rich " standard, which tries to simulate a supercharged condition with ...
In spark-ignition internal combustion engines, knocking (also knock, detonation, spark knock, pinging or pinking) occurs when combustion of some of the air/fuel mixture in the cylinder does not result from propagation of the flame front ignited by the spark plug, but when one or more pockets of air/fuel mixture explode outside the envelope of the normal combustion front.
Fuel additives in the United States are regulated under section 211 of the Clean Air Act (as amended in January 1995). The Environmental Protection Agency (EPA) requires the registration of all fuel additives which are commercially distributed for use in highway motor vehicles in the United States, [8] and may require testing and ban harmful additives.
Heptane or n-heptane is the straight-chain alkane with the chemical formula H 3 C(CH 2) 5 CH 3 or C 7 H 16.When used as a test fuel component in anti-knock test engines, a 100% heptane fuel is the zero point of the octane rating scale (the 100 point is 100% iso-octane).
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Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb(C 2 H 5) 4.It was widely used as a fuel additive for much of the 20th century, first being mixed with gasoline beginning in the 1920s.