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The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.
This equation shows that the temperature decreases exponentially over time, with the rate governed by the properties of the material and the heat transfer coefficient. [7] The heat transfer coefficient, h, is measured in , and represents the transfer of heat at an interface between two materials. This value is different at every interface and ...
The opposite is also true: A Biot number greater than 0.1 (a "thermally thick" substance) indicates that one cannot make this assumption, and more complicated heat transfer equations for "transient heat conduction" will be required to describe the time-varying and non-spatially-uniform temperature field within the material body.
This equation uses the overall heat transfer coefficient of an unfouled heat exchanger and the fouling resistance to calculate the overall heat transfer coefficient of a fouled heat exchanger. The equation takes into account that the perimeter of the heat exchanger is different on the hot and cold sides.
Such spontaneous heat transfer always occurs from a region of high temperature to another region of lower temperature, as described in the second law of thermodynamics. Heat convection occurs when the bulk flow of a fluid (gas or liquid) carries its heat through the fluid. All convective processes also move heat partly by diffusion, as well.
For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
Note that the state equation, given by the first law of thermodynamics (i.e. conservation of energy), is written in the following form (assuming no mass transfer or radiation). This form is more general and particularly useful to recognize which property (e.g. c p or ρ {\displaystyle \rho } ) influences which term.
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.