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The new unit was named the "unified atomic mass unit" and given a new symbol "u", to replace the old "amu" that had been used for the oxygen-based unit. [17] However, the old symbol "amu" has sometimes been used, after 1961, to refer to the new unit, particularly in lay and preparatory contexts.
Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
Conversions between units in the metric system are defined by their prefixes (for example, 1 kilogram = 1000 grams, 1 milligram = 0.001 grams) and are thus not listed in this article. Exceptions are made if the unit is commonly known by another name (for example, 1 micron = 10 −6 metre).
The unified atomic mass unit (symbol: u) is equivalent to the dalton. One dalton is approximately the mass of one a single proton or neutron. [2] The unified atomic mass unit has a value of 1.660 538 921 (73) × 10 −27 kg. [3] The amu without the "unified" prefix is an obsolete unit based on oxygen, which was replaced in 1961.
Hartree defined units based on three physical constants: [1]: 91 Both in order to eliminate various universal constants from the equations and also to avoid high powers of 10 in numerical work, it is convenient to express quantities in terms of units, which may be called 'atomic units', defined as follows:
Atomic mass is often measured in dalton (Da) or unified atomic mass unit (u). One dalton is equal to 1 ⁄ 12 the mass of a carbon-12 atom in its natural state. Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number .
For 12 C, the isotopic mass is exactly 12, since the atomic mass unit is defined as 1/12 of the mass of 12 C. For other isotopes, the isotopic mass is usually within 0.1 u of the mass number. For example, 35 Cl (17 protons and 18 neutrons) has a mass number of 35 and an isotopic mass of 34.96885. [7]
Specifically, the hydrodynamic size as related to molecular mass depends on a conversion factor, describing the shape of a particular molecule. This allows the apparent molecular mass to be described from a range of techniques sensitive to hydrodynamic effects, including DLS , SEC (also known as GPC when the eluent is an organic solvent ...