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Table of specific heat capacities at 25 °C (298 K) unless otherwise noted. [citation needed] Notable minima and maxima are shown in maroon. Substance Phase Isobaric mass heat capacity c P J⋅g −1 ⋅K −1 Molar heat capacity, C P,m and C V,m J⋅mol −1 ⋅K −1 Isobaric volumetric heat capacity C P,v J⋅cm −3 ⋅K −1 Isochoric ...
For example, the heat required to raise the temperature of 1 kg of water by 1 K is 4184 joules, so the specific heat capacity of water is 4184 J⋅kg −1 ⋅K −1. [ 3 ] Specific heat capacity often varies with temperature, and is different for each state of matter .
The "grand calorie" (also "kilocalorie", "kilogram-calorie", or "food calorie"; "kcal" or "Cal") is 1000 cal, that is, exactly 4184 J. It was originally defined so that the heat capacity of 1 kg of water would be 1 kcal/°C. With these units of heat energy, the units of heat capacity are 1 cal/°C = 4.184 J/K ; 1 kcal/°C = 4184 J/K.
Data in the table above is given for water–steam equilibria at various temperatures over the entire temperature range at which liquid water can exist. Pressure of the equilibrium is given in the second column in kPa. The third column is the heat content of each gram of the liquid phase relative to water at 0 °C.
The heat capacity depends on how the external variables of the system are changed when the heat is supplied. If the only external variable of the system is the volume, then we can write: d S = ( ∂ S ∂ T ) V d T + ( ∂ S ∂ V ) T d V {\displaystyle dS=\left({\frac {\partial S}{\partial T}}\right)_{V}dT+\left({\frac {\partial S}{\partial V ...
A closely related property of a substance is the heat capacity per mole of atoms, or atom-molar heat capacity, in which the heat capacity of the sample is divided by the number of moles of atoms instead of moles of molecules. So, for example, the atom-molar heat capacity of water is 1/3 of its molar heat capacity, namely 25.3 J⋅K −1 ⋅mol ...
All values refer to 25 °C and to the thermodynamically stable standard state at that temperature unless noted. Values from CRC refer to "100 kPa (1 bar or 0.987 standard atmospheres)".
Molar heat capacity of most elements at 25 °C is in the range between 2.8 R and 3.4 R: Plot as a function of atomic number with a y range from 22.5 to 30 J/mol K.. The Dulong–Petit law, a thermodynamic law proposed by French physicists Pierre Louis Dulong and Alexis Thérèse Petit, states that the classical expression for the molar specific heat capacity of certain chemical elements is ...