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Cobalt(II) hydroxide precipitates as a solid when an alkali metal hydroxide is added to an aqueous solution of Co 2+ salt. [4] For example, Co 2+ + 2 NaOH → Co(OH) 2 + 2 Na + The compound can be prepared by reacting cobalt(II) nitrate in water with a solution of triethylamine N(C 2 H 5) 3 as both the base and a complexing agent. [3]
Structure of [Co 2 (OH 2) 10] 4+ color code: red = O, white = H, blue = Co. In the binuclear ion [Co 2 (OH 2) 10] 4+ each bridging water molecule donates one pair of electrons to one cobalt ion and another pair to the other cobalt ion. The Co-O (bridging) bond lengths are 213 picometers, and the Co-O (terminal) bond lengths are 10 pm shorter.
The formula, Cu 2 CO 3 (OH) 2 shows that it is halfway between copper carbonate and copper hydroxide. Indeed, in the past the formula was written as CuCO 3 ·Cu(OH) 2. The crystal structure is made up of copper, carbonate and hydroxide ions. [37] The mineral atacamite is an example of a basic chloride. It has the formula, Cu 2 Cl(OH) 3.
Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide.It can be classified as a coordination polymer or a salt.It consists of copper(II) bonded to carbonate and hydroxide with formula Cu 2 (CO 3)(OH) 2.
Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
Skeletal formulae of 1-hydroxy-2()-pyridinethione and its tautomer. The hydroxyl radical, • HO, is the neutral form of the hydroxide ion (HO –).Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry.
CoO + 2 CH 3 CO 2 H + 3 H 2 O → Co(CH 3 CO 2) 2 ·4 H 2 O. The tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central cobalt centre being coordinated by four water molecules and two acetate ligands. [1] The analogous nickel acetate is isostructural. [2]
The mineral of the formula Cu(OH) 2 is called spertiniite. Copper(II) hydroxide is rarely found as an uncombined mineral because it slowly reacts with carbon dioxide from the atmosphere to form a basic copper(II) carbonate. Thus copper(II) hydroxide slowly acquires a dull green coating in moist air by the reaction: 2 Cu(OH) 2 + CO 2 → Cu 2 CO ...