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Oxidation states are typically represented by integers which may be positive, zero, or negative. In some cases, the average oxidation state of an element is a fraction, such as 8 / 3 for iron in magnetite Fe 3 O 4 . The highest known oxidation state is reported to be +9, displayed by iridium in the tetroxoiridium(IX) cation (IrO + 4). [1]
Nitrogen dioxide typically arises via the oxidation of nitric oxide by oxygen in air (e.g. as result of corona discharge): [15] 2 NO + O 2 → 2 NO 2. NO 2 is introduced into the environment by natural causes, including entry from the stratosphere, bacterial respiration, volcanos, and lightning.
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}}
In the solid state it is ionic with structure [NO 2] + [NO 3] −; as a gas and in solution it is molecular O 2 N–O–NO 2. Hydration to nitric acid comes readily, as does analogous reaction with hydrogen peroxide giving peroxonitric acid (HOONO 2). It is a violent oxidising agent. Gaseous dinitrogen pentoxide decomposes as follows: [66]
NO y is the class of compounds comprising NO x and the NO z compounds produced from the oxidation of NO x which include nitric acid, nitrous acid (HONO), dinitrogen pentoxide (N 2 O 5), peroxyacetyl nitrate (PAN), alkyl nitrates (RONO 2), peroxyalkyl nitrates (ROONO 2), the nitrate radical (NO 3), and peroxynitric acid (HNO 4).
The chemical element nitrogen is one of the most abundant elements in the universe and can form many compounds. It can take several oxidation states; but the most common oxidation states are -3 and +3. Nitrogen can form nitride and nitrate ions. It also forms a part of nitric acid and nitrate salts.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
NO y (or NOy) refers to the sum of NO x and all oxidized atmospheric odd-nitrogen species (e.g. the sum of NO x, HNO 3, HNO 2, etc.) NO z (or NOz) = NO y − NO x; Mixed Oxides of Nitrogen ("MON"): solutions of nitric oxide in dinitrogen tetroxide/nitrogen dioxide.