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Indium(III) chloride is the chemical compound with the formula In Cl 3 which forms a tetrahydrate. This salt is a white, flaky solid with applications in organic synthesis as a Lewis acid. It is also the most available soluble derivative of indium. [2] This is one of three known indium chlorides.
Following the discovery of the In 2 Br 6 2− a number of related neutral compounds containing the In II 2 X 4 kernel have been formed from the reaction of indium dihalides with neutral ligands. [14] Some chemists refer to these adducts, when used as the starting point for the synthesis of cluster compounds as ‘In 2 X 4 ’ e.g. the TMEDA ...
Usually such materials feature In–In bonding, most notably in the halides In 2 X 4 and [In 2 X 6] 2−, [43] and various subchalcogenides such as In 4 Se 3. [44] Several other compounds are known to combine indium(I) and indium(III), such as In I 6 (In III Cl 6 )Cl 3 , [ 45 ] In I 5 (In III Br 4 ) 2 (In III Br 6 ), [ 46 ] and In I In III Br 4 .
This reaction gives mixed organoindium halides. Illustrative is the reaction of allyl bromide with a THF suspension of indium. Both monoallylindium dibromide and diallylindium bromide are produced. [5] A variety of organoindium(III) species such as InRX 3− and solvates of RXIn +, R 2 In +, and X 2 In + are thought to rapidly interconvert at ...
Solubility tables; Substance Formula 0 °C 10 °C 15 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Actinium(III) hydroxide
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Reductions with hydrosilanes are methods used for hydrogenation and hydrogenolysis of organic compounds.The approach is a subset of ionic hydrogenation.In this particular method, the substrate is treated with a hydrosilane and auxiliary reagent, often a strong acid, resulting in formal transfer of hydride from silicon to carbon. [1]
Indium dichloride (indium(II) chloride), InCl 2; Indium trichloride (indium(III) chloride), InCl 3 This page was last edited on 21 September ...