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The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate , which cyclopropanates an aromatic ring.
It is commonly thought to be named after the Nobel Laureate Eduard Buchner (without umlaut), but it is actually named after the industrial chemist Ernst Büchner. [2] A Büchner funnel fitted with Sintered Disc made of Boro 3.3 Glass. Diagram of filtration set-up using a Büchner flask
Buchner funnels are made of porcelain and include a plate of sintered glass or perforated porcelain. These are used in filtration under low pressure with a Buchner flask. [2] Hot filtration funnel is a less commonly seen funnel where the funnel is jacketed, and surrounded by a heated fluid. [3]
Eduard Buchner (German: [ˈeːduaʁt ˈbuːxnɐ] ⓘ; 20 May 1860 – 13 August 1917) was a German chemist and zymologist, awarded the 1907 Nobel Prize in Chemistry for his work on fermentation. [ 1 ]
A funnel (E) contains a sample of soil or leaf litter (D), and a heat source (F), in this case an electric lamp (G), heats the sample. Animals escaping from the desiccation of the sample descend through a filter (C) into a preservative liquid (A) in a receptacle (B).
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The Buchner–Curtius–Schlotterbeck reaction is the reaction of aldehydes or ketones with aliphatic diazoalkanes to form homologated ketones. [1] It was first described by Eduard Buchner and Theodor Curtius in 1885 [ 2 ] and later by Fritz Schlotterbeck in 1907. [ 3 ]
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