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Phosphorus pentasulfide is obtained by the reaction of liquid white phosphorus (P 4) with sulfur above 300 °C. The first synthesis of P 4 S 10 by Berzelius in 1843 [ 5 ] was by this method. Alternatively, P 4 S 10 can be formed by reacting elemental sulfur or pyrite , FeS 2 , with ferrophosphorus , a crude form of Fe 2 P (a byproduct of white ...
Phosphorus sulfides comprise a family of inorganic compounds containing only phosphorus and sulfur.These compounds have the formula P 4 S n with n ≤ 10. Two are of commercial significance, phosphorus pentasulfide (P 4 S 10), which is made on a kiloton scale for the production of other organosulfur compounds, and phosphorus sesquisulfide (P 4 S 3), used in the production of "strike anywhere ...
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Potassium pentasulfide is the inorganic compound with the formula K 2 S 5.It is a red-orange solid that dissolves in water. The salt decomposes rapidly in air. It is ...
Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
6 These form water-stable salts. [12] The anion has an ethane-like structure and contains a P−P bond. The formal oxidation state of phosphorus is +4. The oxygen analogue is the hypodiphosphate anion, P 2 O 4− 6. P 3 S 3− 9 contains a six-membered P 3 S 3 ring. The ammonium salt is produced by reaction of P 4 S 10 in liquid ammonia. [13]
Like many sulfides, this compound liberates hydrogen sulfide upon treatment with strong acids such as hydrochloric acid. [3]6 HCl + Sb 2 S 5 → 2 SbCl 3 + 3 H 2 S + 2 S. Analysis by Mössbauer spectroscopy indicates that this compound is a derivative antimony(III), [4] explaining the production of antimony(III) chloride, rather than antimony(V) chloride, upon acidification.
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...