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Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).
When an excited electron falls back to a state of lower energy, it undergoes electron relaxation (deexcitation [4]). This is accompanied by the emission of a photon (radiative relaxation/spontaneous emission) or by a transfer of energy to another particle. The energy released is equal to the difference in energy levels between the electron ...
Any other configuration is an excited state. As an example, the ground state configuration of the sodium atom is 1s 2 2s 2 2p 6 3s 1, as deduced from the Aufbau principle (see below). The first excited state is obtained by promoting a 3s electron to the 3p subshell, to obtain the 1s 2 2s 2 2p 6 3p 1 configuration, abbreviated as the 3p level ...
g state. [2] [3] The ground and first two singlet excited states of oxygen can be described by the simple scheme in the figure below. [7] [8] Molecular orbital diagram of two singlet excited states as well as the triplet ground state of molecular dioxygen. From left to right, the diagrams are for: 1 Δ g singlet oxygen (first excited state), 1 Σ +
The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum.
An asterisk is commonly used to designate an excited state. An electron transition in a molecule's bond from a ground state to an excited state may have a designation such as σ → σ*, π → π*, or n → π* meaning excitation of an electron from a σ bonding to a σ antibonding orbital, from a π bonding to a π antibonding orbital, or ...
For example, the table shows that the first pair of vertically adjacent atoms with different ground-state term symbols are V and Nb. The 6 D 1 ⁄ 2 ground state of Nb corresponds to an excited state of V 2112 cm −1 above the 4 F 3 ⁄ 2 ground state of V, which in turn corresponds to an excited state of Nb 1143 cm −1 above the Nb ground ...
An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb force resulting from their opposite charges. It is an electrically neutral quasiparticle regarded as an elementary excitation primarily in condensed matter, such insulators, semiconductors, some metals, and in some liquids.