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Strictly speaking the above equation holds also for systems with chemical reactions if the terms in the balance equation are taken to refer to total mass, i.e. the sum of all the chemical species of the system. In the absence of a chemical reaction the amount of any chemical species flowing in and out will be the same; this gives rise to an ...
The law of conservation of mass and the analogous law of conservation of energy were finally generalized and unified into the principle of mass–energy equivalence, described by Albert Einstein's equation =. Special relativity also redefines the concept of mass and energy, which can be used interchangeably and are defined relative to the frame ...
Stoichiometry rests upon the very basic laws that help to understand it better, i.e., law of conservation of mass, the law of definite proportions (i.e., the law of constant composition), the law of multiple proportions and the law of reciprocal proportions. In general, chemical reactions combine in definite ratios of chemicals.
The most fundamental concept in chemistry is the law of conservation of mass, which states that there is no detectable change in the quantity of matter during an ordinary chemical reaction. Modern physics shows that it is actually energy that is conserved, and that energy and mass are related ; a concept which becomes important in nuclear ...
All of the conservation laws listed above are local conservation laws. A local conservation law is expressed mathematically by a continuity equation, which states that the change in the quantity in a volume is equal to the total net "flux" of the quantity through the surface of the volume. The following sections discuss continuity equations in ...
The Nernst–Planck equation is a conservation of mass equation used to describe the motion of a charged chemical species in a fluid medium. It extends Fick's law of diffusion for the case where the diffusing particles are also moved with respect to the fluid by electrostatic forces. [1] [2] It is named after Walther Nernst and Max Planck.
The Boltzmann equation can be used to derive the fluid dynamic conservation laws for mass, charge, momentum, and energy. [ 8 ] : 163 For a fluid consisting of only one kind of particle, the number density n is given by n = ∫ f d 3 p . {\displaystyle n=\int f\,d^{3}\mathbf {p} .}
The conservation laws, which in the context of transport phenomena are formulated as continuity equations, describe how the quantity being studied must be conserved. The constitutive equations describe how the quantity in question responds to various stimuli via transport.